TY - JOUR
T1 - A Charge-Based Mechanistic Study into the Effect of Collector Temperature on Melt Electrohydrodynamic Printing Outcomes
AU - Cao, Kai
AU - Zhang, Fucheng
AU - Zaeri, Ahmadreza
AU - Zgeib, Ralf
AU - Chang, Robert C.
N1 - Publisher Copyright:
© 2021 Wiley-VCH GmbH
PY - 2021/7
Y1 - 2021/7
N2 - Melt electrowriting (MEW) is an emerging additive process for high-fidelity, microscale fibrous scaffold fabrication. However, achieving precise multilayered MEW-enabled scaffolds is limited by the entrapped residual charges owing to charge-based mechanisms. Specifically, the semi-conductive nature of processed materials causes retainment of net positive charges and jet–fiber repulsion, while exposure to the electric field yields charge polarization with resultant jet–fiber attraction. These competing effects work in tandem to determine the distinctive features of jet–fiber interaction. To deconstruct various charge-related phenomena, the collector temperature is manipulated as a key process variable to investigate its effect on printing outcomes in two printing modes. Moreover, energy analysis is introduced to explain how collector temperature affects the polarization extent, along with the jet–fiber interaction and printing outcomes. In single fiber printing mode, sets of two parallel fibers with variable set interfiber distances (sSf) are printed at different collector temperatures. At a low sSf threshold, significant fiber attraction is observed, but no significant difference is observed among the cases at different collector temperatures. In scaffold printing mode, 200-layer scaffolds are printed at different collector temperatures, and the wall morphologies are found to vary with location, layer number, and collector temperature.
AB - Melt electrowriting (MEW) is an emerging additive process for high-fidelity, microscale fibrous scaffold fabrication. However, achieving precise multilayered MEW-enabled scaffolds is limited by the entrapped residual charges owing to charge-based mechanisms. Specifically, the semi-conductive nature of processed materials causes retainment of net positive charges and jet–fiber repulsion, while exposure to the electric field yields charge polarization with resultant jet–fiber attraction. These competing effects work in tandem to determine the distinctive features of jet–fiber interaction. To deconstruct various charge-related phenomena, the collector temperature is manipulated as a key process variable to investigate its effect on printing outcomes in two printing modes. Moreover, energy analysis is introduced to explain how collector temperature affects the polarization extent, along with the jet–fiber interaction and printing outcomes. In single fiber printing mode, sets of two parallel fibers with variable set interfiber distances (sSf) are printed at different collector temperatures. At a low sSf threshold, significant fiber attraction is observed, but no significant difference is observed among the cases at different collector temperatures. In scaffold printing mode, 200-layer scaffolds are printed at different collector temperatures, and the wall morphologies are found to vary with location, layer number, and collector temperature.
KW - charge
KW - collector temperature
KW - electrohydrodynamic
KW - melt electrowriting
KW - polarization
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U2 - 10.1002/admt.202100251
DO - 10.1002/admt.202100251
M3 - Article
AN - SCOPUS:85106442374
VL - 6
JO - Advanced Materials Technologies
JF - Advanced Materials Technologies
IS - 7
M1 - 2100251
ER -