A linear polymer manganese(III) complex; synthesis, crystal and molecular structure and magnetic properties of catena-μ-acetato-[N,N′-O-phenylenebis(salicylideneaminato)] manganese(III)

Kou Lin Zhang; Yan Xu; Chang Ge Zheng; Yong Zhang; Zheng Wang; Xiao Zeng You

doi:10.1016/S0020-1693(01)00417-0

A linear polymer manganese(III) complex; synthesis, crystal and molecular structure and magnetic properties of catena-μ-acetato-[N,N′-O-phenylenebis(salicylideneaminato)] manganese(III)

Kou Lin Zhang, Yan Xu, Chang Ge Zheng, Yong Zhang, Zheng Wang, Xiao Zeng You

Department of Chemistry and Chemical Biology

Nanjing University

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

The X-ray structural analyses reveal that the title complex contains the Mn(saloph) [saloph = N,N′-O-phenylenebis(salicylideneaminato)] moieties bridged by single acetato groups in an anti-anti configuration to form linear polymer chains. Variable temperature magnetic susceptibility measurements (4.7-270 K) show the occurrence of very weak antiferromagnetic interactions between the Mn(III) ions with J = - 1.32 cm^-1 and D = - 0.72 cm^-1.

Original language	English
Pages (from-to)	61-66
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	318
Issue number	1-2
DOIs	https://doi.org/10.1016/S0020-1693(01)00417-0
State	Published - 18 Jun 2001

Keywords

Chain complexes
Crystal structures
Magnetic properties
Manganese complexes
Schiff base complexes

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10.1016/S0020-1693(01)00417-0

Cite this

@article{2eee9f241e3947c28d4353c490742924,

title = "A linear polymer manganese(III) complex; synthesis, crystal and molecular structure and magnetic properties of catena-μ-acetato-[N,N′-O-phenylenebis(salicylideneaminato)] manganese(III)",

abstract = "The X-ray structural analyses reveal that the title complex contains the Mn(saloph) [saloph = N,N′-O-phenylenebis(salicylideneaminato)] moieties bridged by single acetato groups in an anti-anti configuration to form linear polymer chains. Variable temperature magnetic susceptibility measurements (4.7-270 K) show the occurrence of very weak antiferromagnetic interactions between the Mn(III) ions with J = - 1.32 cm-1 and D = - 0.72 cm-1.",

keywords = "Chain complexes, Crystal structures, Magnetic properties, Manganese complexes, Schiff base complexes",

author = "Zhang, {Kou Lin} and Yan Xu and Zheng, {Chang Ge} and Yong Zhang and Zheng Wang and You, {Xiao Zeng}",

year = "2001",

month = jun,

day = "18",

doi = "10.1016/S0020-1693(01)00417-0",

language = "English",

volume = "318",

pages = "61--66",

number = "1-2",

}

A linear polymer manganese(III) complex; synthesis, crystal and molecular structure and magnetic properties of catena-μ-acetato-[N,N′-O-phenylenebis(salicylideneaminato)] manganese(III). / Zhang, Kou Lin; Xu, Yan; Zheng, Chang Ge et al.
In: Inorganica Chimica Acta, Vol. 318, No. 1-2, 18.06.2001, p. 61-66.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A linear polymer manganese(III) complex; synthesis, crystal and molecular structure and magnetic properties of catena-μ-acetato-[N,N′-O-phenylenebis(salicylideneaminato)] manganese(III)

AU - Zhang, Kou Lin

AU - Xu, Yan

AU - Zheng, Chang Ge

AU - Zhang, Yong

AU - Wang, Zheng

AU - You, Xiao Zeng

PY - 2001/6/18

Y1 - 2001/6/18

N2 - The X-ray structural analyses reveal that the title complex contains the Mn(saloph) [saloph = N,N′-O-phenylenebis(salicylideneaminato)] moieties bridged by single acetato groups in an anti-anti configuration to form linear polymer chains. Variable temperature magnetic susceptibility measurements (4.7-270 K) show the occurrence of very weak antiferromagnetic interactions between the Mn(III) ions with J = - 1.32 cm-1 and D = - 0.72 cm-1.

AB - The X-ray structural analyses reveal that the title complex contains the Mn(saloph) [saloph = N,N′-O-phenylenebis(salicylideneaminato)] moieties bridged by single acetato groups in an anti-anti configuration to form linear polymer chains. Variable temperature magnetic susceptibility measurements (4.7-270 K) show the occurrence of very weak antiferromagnetic interactions between the Mn(III) ions with J = - 1.32 cm-1 and D = - 0.72 cm-1.

KW - Chain complexes

KW - Crystal structures

KW - Magnetic properties

KW - Manganese complexes

KW - Schiff base complexes

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UR - http://www.scopus.com/inward/citedby.url?scp=0035908275&partnerID=8YFLogxK

U2 - 10.1016/S0020-1693(01)00417-0

DO - 10.1016/S0020-1693(01)00417-0

M3 - Article

AN - SCOPUS:0035908275

SN - 0020-1693

VL - 318

SP - 61

EP - 66

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1-2

ER -

A linear polymer manganese(III) complex; synthesis, crystal and molecular structure and magnetic properties of catena-μ-acetato-[N,N′-O-phenylenebis(salicylideneaminato)] manganese(III)

Abstract

Keywords

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