Ab initio study on far-infrared spectra of dihalodiammine complexes of Palladium(II) and Platinum(II)

L. Zhang, H. Wei, Y. Zhang, Z. Guo, L. Zhu

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

The far-infrared spectra of dihalodiammine complexes of Pd(II) and Pt(II) are calculated using ab initio method at RHF/LANL2DZ level. The calculated vibrational frequencies are in good agreement with the experimental ones except for M-N stretching frequencies in cis-M(NH3)2X2 complexes, and the reason for the deviation is discussed.

Original languageEnglish
Pages (from-to)217-223
Number of pages7
JournalSpectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume58
Issue number2
DOIs
StatePublished - 15 Jan 2002

Keywords

  • Ab initio
  • Configuration
  • Intermolecular interaction
  • Pd(II) and Pt(II) complexes
  • Vibrational frequencies

Fingerprint

Dive into the research topics of 'Ab initio study on far-infrared spectra of dihalodiammine complexes of Palladium(II) and Platinum(II)'. Together they form a unique fingerprint.

Cite this