TY - JOUR
T1 - Catalytic hydrogen-chlorine exchange between chlorinated hydrocarbons under oxygen-free conditions
AU - Van Der Heijden, Alwies W.A.M.
AU - Podkolzin, Simon G.
AU - Jones, Mark E.
AU - Bitter, Johannes H.
AU - Weckhuysen, Bert M.
PY - 2008/6/23
Y1 - 2008/6/23
N2 - (Figure Presented) Pass the parcel: Activity experiments show that LaCl3 supported on carbon nanofibers is a highly active, selective, and stable catalyst for the H-Cl exchange reaction between CCl4 and CH2Cl2 to form CHCl3 (see scheme) in the absence of either lattice or gas-phase oxygen. Density functional calculations suggest that the reaction proceeds through the formation of weakly adsorbed Cl and H species which can be exchanged between the reactants.
AB - (Figure Presented) Pass the parcel: Activity experiments show that LaCl3 supported on carbon nanofibers is a highly active, selective, and stable catalyst for the H-Cl exchange reaction between CCl4 and CH2Cl2 to form CHCl3 (see scheme) in the absence of either lattice or gas-phase oxygen. Density functional calculations suggest that the reaction proceeds through the formation of weakly adsorbed Cl and H species which can be exchanged between the reactants.
KW - Density functional calculations
KW - Heterogeneous catalysis
KW - Lanthanum
KW - Metathesis
KW - Supported catalysts
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U2 - 10.1002/anie.200800270
DO - 10.1002/anie.200800270
M3 - Article
AN - SCOPUS:53549114527
SN - 1433-7851
VL - 47
SP - 5002
EP - 5004
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 27
ER -