Creation of ultracold molecules within the lifetime scale by direct implementation of an optical frequency comb

A method is proposed to create molecules in the ultracold state from the Feshbach molecules by stepwise adiabatic passage using an optical frequency comb without losses due to decoherence. An emphasis is made on the impact of the vibrational state manifold on controllability of the coherent dynamics by including five excited states into the model. The results are compared with recently reported results on a three-level (Formula presented.) system. Sinusoidal modulation across an individual pulse in the pulse train is applied, leading to the creation of a quasi-dark state, which minimizes population of the transitional, vibrational state manifold, and efficiently mitigates decoherence in the system. The parity of the temporal chirp is shown to be an important factor in designing population dynamics in the system.