TY - JOUR
T1 - Identification of catalytic active oxygen species on alumina-supported silver nanoparticles with in situ Raman spectroscopy and DFT calculations
AU - Chen, Tao
AU - Jehng, Jih Mirn
AU - Pal, Amrita
AU - Podkolzin, Simon G.
AU - Wachs, Israel E.
PY - 2011
Y1 - 2011
N2 - The nature of catalytic active oxygen species in ethylene epoxidation was studied using a series of supported Ag/Al2O3 catalysts. In situ Raman spectra were collected as a function of temperature and oxygen exposure and found to exhibit bands in three regions: (1) below 500, (2) 700-900 and (3) above 900 cm-1. DFT calculations with vibrational analyses using metallic Ag, Ag2O and Ag surfaces with a variable extent of oxidation were performed for the first time in order to elucidate the assignment of the vibrational bands. The low wavenumber region is assigned to chemisorbed atomic oxygen. The highest wavenumber region is assigned to chemisorbed molecular O2. The intermediate wavenumber region, which is associated with catalytic active oxygen, is for the first time shown to be inconsistent with the traditional assignment of atomic oxygen bound to Ag. Our spectroscopic and computational results suggest that atomic oxygen binds to the lattice oxygen of oxidized Ag, forming hybrid O-O (adsorbed O - lattice O) surface species. The in situ Raman studies also revealed that the "hybrid" O-O surface species are preferentially consumed during selective oxidation of ethylene to ethylene oxide.
AB - The nature of catalytic active oxygen species in ethylene epoxidation was studied using a series of supported Ag/Al2O3 catalysts. In situ Raman spectra were collected as a function of temperature and oxygen exposure and found to exhibit bands in three regions: (1) below 500, (2) 700-900 and (3) above 900 cm-1. DFT calculations with vibrational analyses using metallic Ag, Ag2O and Ag surfaces with a variable extent of oxidation were performed for the first time in order to elucidate the assignment of the vibrational bands. The low wavenumber region is assigned to chemisorbed atomic oxygen. The highest wavenumber region is assigned to chemisorbed molecular O2. The intermediate wavenumber region, which is associated with catalytic active oxygen, is for the first time shown to be inconsistent with the traditional assignment of atomic oxygen bound to Ag. Our spectroscopic and computational results suggest that atomic oxygen binds to the lattice oxygen of oxidized Ag, forming hybrid O-O (adsorbed O - lattice O) surface species. The in situ Raman studies also revealed that the "hybrid" O-O surface species are preferentially consumed during selective oxidation of ethylene to ethylene oxide.
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M3 - Conference article
AN - SCOPUS:80051908728
SN - 0065-7727
JO - ACS National Meeting Book of Abstracts
JF - ACS National Meeting Book of Abstracts
T2 - 241st ACS National Meeting and Exposition
Y2 - 27 March 2011 through 31 March 2011
ER -