Insight into mixed chlorine/chloramines conversion and associated water quality variability in drinking water distribution systems

Mixed chlorine/chloramines are common in drinking water distribution systems (DWDSs); however, their transformation and impact on chemical and microbial characteristics are not well understood. We systematically investigated water quality parameters associated with mixed chlorine/chloramine species conversion in 192 samples (including raw, finished, and tap water) collected throughout the year in a city in East China. Various chlorine/chloramine species (free chlorine, monochloramine [NH₂Cl], dichloramine [NHCl₂], and organic chloramines [OC]) were detected in both chlorinated and chloraminated DWDSs. NHCl₂ + OC increased with transport distance along the pipeline network. The maximum proportion of NHCl₂ + OC in over total chlorine in tap water reached 66 % and 38 % from chlorinated and chloraminated DWDSs, respectively. Both free chlorine and NH₂Cl showed a rapid decay in the water pipe systems, but NHCl₂ and OC were more persistent. Correlations between chlorine/chloramine species and physicochemical parameters were established. Models for predicting the sum of chloroform/TCM, bromodichloromethane/BDCM, chlorodibromomethane/CBDM, and bromoform/TBM (THM₄) (R² = 0.56) and haloacetic acids (HAAs) (R² = 0.65) exhibited greater accuracy based on machine learning tuned with chlorine/chloramine species, particularly NHCl₂ + OC. The predominant bacterial communities in mixed chlorine/chloramine systems were those resistant to chlorine or chloramine such as proteobacteria. NH₂Cl was the most significant explanatory factor (28.1 %) for the variation in microbial community assemblage in chloraminated DWDSs. Although residual free chlorine and NHCl₂ + OC, accounted for a smaller proportion of chlorine species in chloraminated DWDSs, they played an essential role (12.4 % and 9.1 %, respectively) in the microbial community structure.