Abstract
The recently reported 19F-detected dual-optimized inverted 1JCC 1,n-ADEQUATE experiment and the previously reported 1H-detected version have been modified to incorporate J-modulation, making it feasible to acquire all 1,1- and 1,n-ADEQUATE correlations as well as 1JCC and nJCC homonuclear scalar couplings in a single experiment. The experiments are demonstrated using N,N-dimethylamino-2,5,6-trifluoro-3,4-phthalonitrile and N,N-dimethylamino-3,4-phthalonitrile.
Original language | English |
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Pages (from-to) | 169-179 |
Number of pages | 11 |
Journal | Magnetic Resonance in Chemistry |
Volume | 61 |
Issue number | 3 |
DOIs | |
State | Published - Mar 2023 |
Keywords
- 1,1-ADEQUATE
- 1,n-ADEQUATE
- F-detection
- H-detection
- J
- J
- J-modulation
- dual-optimization
- inverted J correlations