J-modulated 19F- and 1H-detected dual-optimized inverted 1JCC 1,n-ADEQUATE: A universal ADEQUATE experiment

Ronald C. Crouch; Marius Pelmuş; Jeffrey G. Raab; Evgeny Tischenko; Michael Frey; Yunyi Wang; Mikhail Reibarkh; R. Thomas Williamson; Gary E. Martin

doi:10.1002/mrc.5324

J-modulated ¹⁹F- and ¹H-detected dual-optimized inverted ¹J_CC 1,n-ADEQUATE: A universal ADEQUATE experiment

Ronald C. Crouch
, Marius Pelmuş
, Jeffrey G. Raab
, Evgeny Tischenko
, Michael Frey
, Yunyi Wang
, Mikhail Reibarkh
, R. Thomas Williamson
, Gary E. Martin

Department of Chemistry and Chemical Biology

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The recently reported ¹⁹F-detected dual-optimized inverted ¹J_CC 1,n-ADEQUATE experiment and the previously reported ¹H-detected version have been modified to incorporate J-modulation, making it feasible to acquire all 1,1- and 1,n-ADEQUATE correlations as well as ¹J_CC and ⁿJ_CC homonuclear scalar couplings in a single experiment. The experiments are demonstrated using N,N-dimethylamino-2,5,6-trifluoro-3,4-phthalonitrile and N,N-dimethylamino-3,4-phthalonitrile.

Original language	English
Pages (from-to)	169-179
Number of pages	11
Journal	Magnetic Resonance in Chemistry
Volume	61
Issue number	3
DOIs	https://doi.org/10.1002/mrc.5324
State	Published - Mar 2023

Keywords

1,1-ADEQUATE
1,n-ADEQUATE
F-detection
H-detection
J
J
J-modulation
dual-optimization
inverted J correlations

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10.1002/mrc.5324

Cite this

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title = "J-modulated 19F- and 1H-detected dual-optimized inverted 1JCC 1,n-ADEQUATE: A universal ADEQUATE experiment",

abstract = "The recently reported 19F-detected dual-optimized inverted 1JCC 1,n-ADEQUATE experiment and the previously reported 1H-detected version have been modified to incorporate J-modulation, making it feasible to acquire all 1,1- and 1,n-ADEQUATE correlations as well as 1JCC and nJCC homonuclear scalar couplings in a single experiment. The experiments are demonstrated using N,N-dimethylamino-2,5,6-trifluoro-3,4-phthalonitrile and N,N-dimethylamino-3,4-phthalonitrile.",

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year = "2023",

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doi = "10.1002/mrc.5324",

language = "English",

volume = "61",

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T2 - A universal ADEQUATE experiment

AU - Crouch, Ronald C.

AU - Pelmuş, Marius

AU - Raab, Jeffrey G.

AU - Tischenko, Evgeny

AU - Frey, Michael

AU - Wang, Yunyi

AU - Reibarkh, Mikhail

AU - Williamson, R. Thomas

AU - Martin, Gary E.

PY - 2023/3

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AB - The recently reported 19F-detected dual-optimized inverted 1JCC 1,n-ADEQUATE experiment and the previously reported 1H-detected version have been modified to incorporate J-modulation, making it feasible to acquire all 1,1- and 1,n-ADEQUATE correlations as well as 1JCC and nJCC homonuclear scalar couplings in a single experiment. The experiments are demonstrated using N,N-dimethylamino-2,5,6-trifluoro-3,4-phthalonitrile and N,N-dimethylamino-3,4-phthalonitrile.

KW - 1,1-ADEQUATE

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KW - F-detection

KW - H-detection

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KW - J-modulation

KW - dual-optimization

KW - inverted J correlations

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UR - https://www.scopus.com/pages/publications/85142653084#tab=citedBy

U2 - 10.1002/mrc.5324

DO - 10.1002/mrc.5324

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JO - Magnetic Resonance in Chemistry

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J-modulated ¹⁹F- and ¹H-detected dual-optimized inverted ¹J_CC 1,n-ADEQUATE: A universal ADEQUATE experiment

Abstract

Keywords

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