Keggin unit supported transition metal complexes: Hydrothermal synthesis and characterization

Yan Xu; Ji Qing Xu; Kou Lin Zhang; Yong Zhang; Xiao Zeng You

doi:10.1039/a908527k

Keggin unit supported transition metal complexes: Hydrothermal synthesis and characterization

Yan Xu
, Ji Qing Xu
, Kou Lin Zhang
, Yong Zhang
, Xiao Zeng You

Department of Chemistry and Chemical Biology

Nanjing University
Jilin University

Research output: Contribution to journal › Article › peer-review

192 Scopus citations

Abstract

Two new Keggin unit supported transition metal complexes, [Ni(2,2'- bipy)₃]_1.5[PW₁₂O₄₀Ni(2,2'-bipy)₂(H₂0)] · 0.5H₂O 1 and [Co(1,10'- phen)₃]_1.5[PMo₁₂O₄₀Co(1,10',-phen)₂(H₂O)] · 0.5H₂O 2, are synthesized by a hydrothermal method; complex 1 is characterized by X-ray crystallography, showing that the [Ni(2,2'-bipy)₂(H₂O)]²⁺ units are covalently bonded to the α-Keggin cluster [PW(v)₂-W(VI)₁₀O₄₀]^5-.

Original language	English
Pages (from-to)	153-154
Number of pages	2
Journal	Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/a908527k
State	Published - 21 Jan 2000

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title = "Keggin unit supported transition metal complexes: Hydrothermal synthesis and characterization",

abstract = "Two new Keggin unit supported transition metal complexes, [Ni(2,2'- bipy)3]1.5[PW12O40Ni(2,2'-bipy)2(H20)] · 0.5H2O 1 and [Co(1,10'- phen)3]1.5[PMo12O40Co(1,10',-phen)2(H2O)] · 0.5H2O 2, are synthesized by a hydrothermal method; complex 1 is characterized by X-ray crystallography, showing that the [Ni(2,2'-bipy)2(H2O)]2+ units are covalently bonded to the α-Keggin cluster [PW(v)2-W(VI)10O40]5-.",

author = "Yan Xu and Xu, \{Ji Qing\} and Zhang, \{Kou Lin\} and Yong Zhang and You, \{Xiao Zeng\}",

year = "2000",

month = jan,

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doi = "10.1039/a908527k",

language = "English",

pages = "153--154",

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TY - JOUR

T1 - Keggin unit supported transition metal complexes

T2 - Hydrothermal synthesis and characterization

AU - Xu, Yan

AU - Xu, Ji Qing

AU - Zhang, Kou Lin

AU - Zhang, Yong

AU - You, Xiao Zeng

PY - 2000/1/21

Y1 - 2000/1/21

N2 - Two new Keggin unit supported transition metal complexes, [Ni(2,2'- bipy)3]1.5[PW12O40Ni(2,2'-bipy)2(H20)] · 0.5H2O 1 and [Co(1,10'- phen)3]1.5[PMo12O40Co(1,10',-phen)2(H2O)] · 0.5H2O 2, are synthesized by a hydrothermal method; complex 1 is characterized by X-ray crystallography, showing that the [Ni(2,2'-bipy)2(H2O)]2+ units are covalently bonded to the α-Keggin cluster [PW(v)2-W(VI)10O40]5-.

AB - Two new Keggin unit supported transition metal complexes, [Ni(2,2'- bipy)3]1.5[PW12O40Ni(2,2'-bipy)2(H20)] · 0.5H2O 1 and [Co(1,10'- phen)3]1.5[PMo12O40Co(1,10',-phen)2(H2O)] · 0.5H2O 2, are synthesized by a hydrothermal method; complex 1 is characterized by X-ray crystallography, showing that the [Ni(2,2'-bipy)2(H2O)]2+ units are covalently bonded to the α-Keggin cluster [PW(v)2-W(VI)10O40]5-.

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U2 - 10.1039/a908527k

DO - 10.1039/a908527k

M3 - Article

AN - SCOPUS:0034695555

SN - 1359-7345

SP - 153

EP - 154

JO - Chemical Communications

JF - Chemical Communications

IS - 2

ER -

Keggin unit supported transition metal complexes: Hydrothermal synthesis and characterization

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