Abstract
A technique for calculating magnetic susceptibility of dimeric octahedral Co(II) complexes with a paramagnetic ligand allowing for exchange interactions between dimers is developed within the molecular-field approximation. Model calculations are performed. From an analysis of the experimental data on magnetic susceptibility values of parameters J = 61 cm-1 of intramolecular Ĥexch = - 2JŜCoŜL) and J'n = 4.6 cm-1 and of intermolecular (Ĥ'exch = -2J'nΣŜu 〈Su〉 exchange interactions, ferromagnetic in nature, are determined for a new Co(II) complex compound with a 4-amido-2,2-dimethyl-5,5-dimethoxy-3-imidazoline-1-oxyl radical.
Original language | English |
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Pages (from-to) | 1171-1179 |
Number of pages | 9 |
Journal | Chemical Physics Reports |
Volume | 15 |
Issue number | 8 |
State | Published - 1996 |