New charge transfer complexes from dicyanodihydrofullerene and metallocene

Suo Zhiyong, Wei Xianwen, Zhou Keyu, Zhang Yong, Li Chongde, Xu Zheng

Research output: Contribution to journalArticlepeer-review

Abstract

Novel charge transfer complexes based on MCp2 (M = Co or Ni) and dicyanodihydrofullerene [C60(CN)2] have been prepared and the charge transfer in them investigated by UV-NIR, EPR and other spectra. The dicyanodihydrofullerene was reduced to the monoanion in the compound CoCp2·C60(CN)2·CS2, which showed a characteristic NIR band at 1016 nm.

Original languageEnglish
Pages (from-to)3875-3878
Number of pages4
JournalJournal of the Chemical Society - Dalton Transactions
Issue number22
StatePublished - 21 Nov 1998

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