TY - JOUR
T1 - Quantitative Investigation into the Design and Process Parametric Effects on the Fiber-Entrapped Residual Charge for a Polymer Melt Electrohydrodynamic Printing Process
AU - Cao, Kai
AU - Zhang, Fucheng
AU - Zaeri, Ahmadreza
AU - Zgeib, Ralf
AU - Chang, Robert C.
N1 - Publisher Copyright:
© 2022 Wiley-VCH GmbH
PY - 2022/3
Y1 - 2022/3
N2 - The printing accuracy of the melt electrowriting (MEW) process is adversely affected by residual charge entrapped within the printed fibers. To mitigate this effect, the residual charge amount (Qr) must first be accurately determined. In this study, Qr is measured by a commercial electrometer at a nanocoulomb scale for MEW-enabled scaffolds. Based on this enabling measurement, the effects of various design parameters (including substrate surface conductivity σ, printing time t, layer number N), and process parameters (including voltage U, translational stage speed v, and material temperature Tm), on Qr are investigated. An increase of σ or decrease of N helps to decrease Qr. The effects of different process parameters on the residual charge can be either dependent or independent of fiber morphologies. Moreover, the fiber-morphology dependent and independent effect can be either synergistic (U and Tm) or antagonistic (e.g., v) for different process parameters. Under same conditions, Qr in the interweaving scaffold design is generally smaller than that in the non-interweaving scaffold design. These results help to furnish necessary insights into the charge dissipation process for a melt-based electrohydrodynamic printing process while providing a systematic methodology to mitigate the residual charge accumulation.
AB - The printing accuracy of the melt electrowriting (MEW) process is adversely affected by residual charge entrapped within the printed fibers. To mitigate this effect, the residual charge amount (Qr) must first be accurately determined. In this study, Qr is measured by a commercial electrometer at a nanocoulomb scale for MEW-enabled scaffolds. Based on this enabling measurement, the effects of various design parameters (including substrate surface conductivity σ, printing time t, layer number N), and process parameters (including voltage U, translational stage speed v, and material temperature Tm), on Qr are investigated. An increase of σ or decrease of N helps to decrease Qr. The effects of different process parameters on the residual charge can be either dependent or independent of fiber morphologies. Moreover, the fiber-morphology dependent and independent effect can be either synergistic (U and Tm) or antagonistic (e.g., v) for different process parameters. Under same conditions, Qr in the interweaving scaffold design is generally smaller than that in the non-interweaving scaffold design. These results help to furnish necessary insights into the charge dissipation process for a melt-based electrohydrodynamic printing process while providing a systematic methodology to mitigate the residual charge accumulation.
KW - contact discharge
KW - fiber morphology
KW - melt electrowriting
KW - residual charge
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U2 - 10.1002/mame.202100766
DO - 10.1002/mame.202100766
M3 - Article
AN - SCOPUS:85123121967
SN - 1438-7492
VL - 307
JO - Macromolecular Materials and Engineering
JF - Macromolecular Materials and Engineering
IS - 3
M1 - 2100766
ER -