TY - JOUR
T1 - Quantum transport in graphene nanoribbons with realistic edges
AU - Hawkins, Patrick
AU - Begliarbekov, Milan
AU - Zivkovic, Marko
AU - Strauf, Stefan
AU - Search, Christopher P.
PY - 2012/8/30
Y1 - 2012/8/30
N2 - Due to their unique electrical properties, graphene nanoribbons (GNRs) show great promise as the building blocks of novel electronic devices. However, these properties are strongly dependent on the geometry of the edges of the graphene devices. Thus far, only zigzag and armchair edges have been extensively studied. However, several other self-passivating edge reconstructions are possible, and were experimentally observed. Here we utilize the nonequilibrium Greens function (NEGF) technique in conjunction with tight binding methods to model quantum transport through armchair, zigzag, and several other self-passivated edge reconstructions. In addition, we consider the experimentally relevant cases of mixed edges, where random combinations of possible terminations exist on a given GNR boundary. We find that transport through GNRs with self-passivating edge reconstructions is governed by the sublattice structure of the edges, in a manner similar to their parent zigzag or armchair configurations. Furthermore, we find that the reconstructed armchair GNRs have a larger band gap energy than pristine armchair edges and are more robust against edge disorder. These results offer novel insights into the transport in GNRs with realistic edges and are thus of paramount importance in the development of GNR based devices.
AB - Due to their unique electrical properties, graphene nanoribbons (GNRs) show great promise as the building blocks of novel electronic devices. However, these properties are strongly dependent on the geometry of the edges of the graphene devices. Thus far, only zigzag and armchair edges have been extensively studied. However, several other self-passivating edge reconstructions are possible, and were experimentally observed. Here we utilize the nonequilibrium Greens function (NEGF) technique in conjunction with tight binding methods to model quantum transport through armchair, zigzag, and several other self-passivated edge reconstructions. In addition, we consider the experimentally relevant cases of mixed edges, where random combinations of possible terminations exist on a given GNR boundary. We find that transport through GNRs with self-passivating edge reconstructions is governed by the sublattice structure of the edges, in a manner similar to their parent zigzag or armchair configurations. Furthermore, we find that the reconstructed armchair GNRs have a larger band gap energy than pristine armchair edges and are more robust against edge disorder. These results offer novel insights into the transport in GNRs with realistic edges and are thus of paramount importance in the development of GNR based devices.
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U2 - 10.1021/jp304676h
DO - 10.1021/jp304676h
M3 - Article
AN - SCOPUS:84865734170
SN - 1932-7447
VL - 116
SP - 18382
EP - 18387
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
IS - 34
ER -