Self-assembly and X-ray structure determination of the novel 2-D layered organic-inorganic hybrid Pb-X compound: [PbX2(4,4′-bipy)]n (X = I, Br)

Yu Jun Shi, Yan Xu, Yong Zhang, Bin Huang, Dun Ru Zhu, Chuan Ming Jin, Hao Guo Zhu, Zhi Yu, Xue Tai Chen, Xiao Zeng You

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Abstract

Two novel organic-inorganic hybrid compounds, [PbI2(4,4′-bipy)]n (1) and [PbBr2(4,4′-bipy)]n (2), are synthesized by self-assembly. X-ray crystallography analysis shows that the [PbI2]n chains in 1 are linked by 4,4′-bipyridine to form a layer, via Pb-N bonding along the direction of the 'b' axis.

Original languageEnglish
Pages (from-to)678-679
Number of pages2
JournalChemistry Letters
Issue number7
DOIs
StatePublished - 2001

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