Spectroscopic and computational study of cr oxide structures and their anchoring sites on ZSM-5 zeolites

Jie Gao, Yiteng Zheng, Yadan Tang, Jih Mirn Jehng, Robert Grybos, Jaroslaw Handzlik, Israel E. Wachs, Simon G. Podkolzin

Research output: Contribution to journalArticlepeer-review

74 Scopus citations

Abstract

Cr/ZSM-5 catalysts with 0.5-2.6 wt % Cr loadings and zeolites with 15-140 Si/Al ratios were characterized with in situ UV-vis, IR, and Raman spectroscopies, including operando Raman measurements under reaction conditions in methane conversion at 773-1123 K with a simultaneous online analysis of reaction products. DFT calculations with cluster and periodic models were performed with DMol3, Gaussian 09, and VASP software packages. Isolated Cr(VI) dioxo and Cr(III) mono-oxo structures on framework Al anchoring sites were identified as the dominant species under most conditions. In the absence of gas-phase O2 (under Ar flow) at 773 K, the Cr(VI) dioxo species on framework Al anchoring sites autoreduce, and the Cr(III) mono-oxo species remain the only observable surface Cr oxide structures. For ZSM-5 zeolites with a relatively low concentration of framework Al atoms (Si/Al ≥ 25), exposure to gas-phase O2 at 773 K forces surface Cr oxide species to migrate from framework Al anchoring sites to Si sites on the external surface of the zeolite and form dioxo (Si-O-)2Cr(=O)2 and mono-oxo (Si-O-)4Cr(=O) structures. The activity of Cr/ZSM-5 catalysts in methane conversion with the production of benzene and hydrogen as the main products is lower than that of Mo/ZSM-5 catalysts. The rate of benzene formation over Cr/ZSM-5 catalysts, however, is relatively stable with time on stream, in comparison to a rapidly declining rate over Mo/ZSM-5 catalysts. The zeolite-supported Cr species are highly mobile under the reaction conditions and can migrate between zeolite particles.

Original languageEnglish
Pages (from-to)3078-3092
Number of pages15
JournalACS Catalysis
Volume5
Issue number5
DOIs
StatePublished - 1 May 2015

Keywords

  • Cr/ZSM-5
  • DFT calculations
  • Raman spectroscopy
  • methane dehydroaromatization
  • zeolite

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