TY - JOUR
T1 - Synthesis and crystal structure of a novel 2-D hybrid compound [(PbBr2)2(μ-Pyz)]n (Pyz = pyrazine)
AU - Shi, Yu Jun
AU - Chen, Xue Tai
AU - Cai, Chen Xin
AU - Zhang, Yong
AU - Xue, Ziling
AU - You, Xiao Zeng
AU - Peng, Shi Ming
AU - Lee, Gene Hsiang
PY - 2002
Y1 - 2002
N2 - A novel 2-D organic-inorganic hybrid compound [(PbBr2)2(μ-Pyz)]n 1, has been prepared, and its x-ray structure shows that the supramolecular structure consists of organic-inorganic hybrid layers, each of which is constructed from two [PbBr2]n sheets and one pyrazine, via Pb-N bonding along the direction of the b-axis, and the divalent lead is penta-coordinated to form a hemidirected complex.
AB - A novel 2-D organic-inorganic hybrid compound [(PbBr2)2(μ-Pyz)]n 1, has been prepared, and its x-ray structure shows that the supramolecular structure consists of organic-inorganic hybrid layers, each of which is constructed from two [PbBr2]n sheets and one pyrazine, via Pb-N bonding along the direction of the b-axis, and the divalent lead is penta-coordinated to form a hemidirected complex.
KW - Hemidirected complex
KW - Organic-inorganic hybrid
KW - Pyrazine
KW - Supramolecular structure
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U2 - 10.1016/S1387-7003(02)00508-7
DO - 10.1016/S1387-7003(02)00508-7
M3 - Article
AN - SCOPUS:0036327393
SN - 1387-7003
VL - 5
SP - 621
EP - 624
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
IS - 8
ER -