Synthesis and crystal structure of a novel 2-D hybrid compound [(PbBr2)2(μ-Pyz)]n (Pyz = pyrazine)

Yu Jun Shi, Xue Tai Chen, Chen Xin Cai, Yong Zhang, Ziling Xue, Xiao Zeng You, Shi Ming Peng, Gene Hsiang Lee

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

A novel 2-D organic-inorganic hybrid compound [(PbBr2)2(μ-Pyz)]n 1, has been prepared, and its x-ray structure shows that the supramolecular structure consists of organic-inorganic hybrid layers, each of which is constructed from two [PbBr2]n sheets and one pyrazine, via Pb-N bonding along the direction of the b-axis, and the divalent lead is penta-coordinated to form a hemidirected complex.

Original languageEnglish
Pages (from-to)621-624
Number of pages4
JournalInorganic Chemistry Communications
Volume5
Issue number8
DOIs
StatePublished - 2002

Keywords

  • Hemidirected complex
  • Organic-inorganic hybrid
  • Pyrazine
  • Supramolecular structure

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