Synthesis and crystal structure of a novel 2-D hybrid compound [(PbBr2)2(μ-Pyz)]n (Pyz = pyrazine)

Yu Jun Shi; Xue Tai Chen; Chen Xin Cai; Yong Zhang; Ziling Xue; Xiao Zeng You; Shi Ming Peng; Gene Hsiang Lee

doi:10.1016/S1387-7003(02)00508-7

Synthesis and crystal structure of a novel 2-D hybrid compound [(PbBr₂)₂(μ-Pyz)]_n (Pyz = pyrazine)

Yu Jun Shi
, Xue Tai Chen
, Chen Xin Cai
, Yong Zhang
, Ziling Xue
, Xiao Zeng You
, Shi Ming Peng
, Gene Hsiang Lee

Department of Chemistry and Chemical Biology

Nanjing University
University of Tennessee, Knoxville
National Taiwan University

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

A novel 2-D organic-inorganic hybrid compound [(PbBr₂)₂(μ-Pyz)]_n 1, has been prepared, and its x-ray structure shows that the supramolecular structure consists of organic-inorganic hybrid layers, each of which is constructed from two [PbBr₂]_n sheets and one pyrazine, via Pb-N bonding along the direction of the b-axis, and the divalent lead is penta-coordinated to form a hemidirected complex.

Original language	English
Pages (from-to)	621-624
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	5
Issue number	8
DOIs	https://doi.org/10.1016/S1387-7003(02)00508-7
State	Published - 2002

Keywords

Hemidirected complex
Organic-inorganic hybrid
Pyrazine
Supramolecular structure

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10.1016/S1387-7003(02)00508-7

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title = "Synthesis and crystal structure of a novel 2-D hybrid compound [(PbBr2)2(μ-Pyz)]n (Pyz = pyrazine)",

abstract = "A novel 2-D organic-inorganic hybrid compound [(PbBr2)2(μ-Pyz)]n 1, has been prepared, and its x-ray structure shows that the supramolecular structure consists of organic-inorganic hybrid layers, each of which is constructed from two [PbBr2]n sheets and one pyrazine, via Pb-N bonding along the direction of the b-axis, and the divalent lead is penta-coordinated to form a hemidirected complex.",

keywords = "Hemidirected complex, Organic-inorganic hybrid, Pyrazine, Supramolecular structure",

author = "Shi, \{Yu Jun\} and Chen, \{Xue Tai\} and Cai, \{Chen Xin\} and Yong Zhang and Ziling Xue and You, \{Xiao Zeng\} and Peng, \{Shi Ming\} and Lee, \{Gene Hsiang\}",

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doi = "10.1016/S1387-7003(02)00508-7",

language = "English",

volume = "5",

pages = "621--624",

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TY - JOUR

T1 - Synthesis and crystal structure of a novel 2-D hybrid compound [(PbBr2)2(μ-Pyz)]n (Pyz = pyrazine)

AU - Shi, Yu Jun

AU - Chen, Xue Tai

AU - Cai, Chen Xin

AU - Zhang, Yong

AU - Xue, Ziling

AU - You, Xiao Zeng

AU - Peng, Shi Ming

AU - Lee, Gene Hsiang

PY - 2002

Y1 - 2002

N2 - A novel 2-D organic-inorganic hybrid compound [(PbBr2)2(μ-Pyz)]n 1, has been prepared, and its x-ray structure shows that the supramolecular structure consists of organic-inorganic hybrid layers, each of which is constructed from two [PbBr2]n sheets and one pyrazine, via Pb-N bonding along the direction of the b-axis, and the divalent lead is penta-coordinated to form a hemidirected complex.

AB - A novel 2-D organic-inorganic hybrid compound [(PbBr2)2(μ-Pyz)]n 1, has been prepared, and its x-ray structure shows that the supramolecular structure consists of organic-inorganic hybrid layers, each of which is constructed from two [PbBr2]n sheets and one pyrazine, via Pb-N bonding along the direction of the b-axis, and the divalent lead is penta-coordinated to form a hemidirected complex.

KW - Hemidirected complex

KW - Organic-inorganic hybrid

KW - Pyrazine

KW - Supramolecular structure

UR - https://www.scopus.com/pages/publications/0036327393

UR - https://www.scopus.com/pages/publications/0036327393#tab=citedBy

U2 - 10.1016/S1387-7003(02)00508-7

DO - 10.1016/S1387-7003(02)00508-7

M3 - Article

AN - SCOPUS:0036327393

SN - 1387-7003

VL - 5

SP - 621

EP - 624

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 8

ER -

Synthesis and crystal structure of a novel 2-D hybrid compound [(PbBr₂)₂(μ-Pyz)]_n (Pyz = pyrazine)

Abstract

Keywords

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