Synthesis, crystal and molecular structure and magnetic properties of [Mn(saloph)(N3)(Ch3OH)]

Kou Lin Zhang, Yan Xu, You Song, Yong Zhang, Zheng Wang, Xiao Zeng You

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

The mononuclear manganese(III) complex of formula [Mn(saloph)(N3)(CH3OH)] [saloph = N,N'-o-phenylenebis(salicylidenaminato)] has been synthesized and its crystal structure has been determined by single-crystal X-ray diffraction method. The compound has a 1D hydrogen-bonded extended structure. Both the FT-IR spectrum and the electrospray ionization mass spectrum (ESI-MS) of the title compound have been recorded. The thermogravimetric analysis has also been carried out. Magnetic calculations showed the presence of antiferromagnetic exchange interactions between the manganese(III) ions through hydrogen bonds with J = -4.0 cm-1.

Original languageEnglish
Pages (from-to)137-143
Number of pages7
JournalJournal of Molecular Structure
Volume570
Issue number1-3
DOIs
StatePublished - 1 Aug 2001

Keywords

  • ID extended structure
  • Magnetic properties
  • Manganese(III) complex
  • Schiff base complex
  • Synthesis

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