TY - JOUR
T1 - Synthesis, crystal and molecular structure and magnetic properties of [Mn(saloph)(N3)(Ch3OH)]
AU - Zhang, Kou Lin
AU - Xu, Yan
AU - Song, You
AU - Zhang, Yong
AU - Wang, Zheng
AU - You, Xiao Zeng
PY - 2001/8/1
Y1 - 2001/8/1
N2 - The mononuclear manganese(III) complex of formula [Mn(saloph)(N3)(CH3OH)] [saloph = N,N'-o-phenylenebis(salicylidenaminato)] has been synthesized and its crystal structure has been determined by single-crystal X-ray diffraction method. The compound has a 1D hydrogen-bonded extended structure. Both the FT-IR spectrum and the electrospray ionization mass spectrum (ESI-MS) of the title compound have been recorded. The thermogravimetric analysis has also been carried out. Magnetic calculations showed the presence of antiferromagnetic exchange interactions between the manganese(III) ions through hydrogen bonds with J = -4.0 cm-1.
AB - The mononuclear manganese(III) complex of formula [Mn(saloph)(N3)(CH3OH)] [saloph = N,N'-o-phenylenebis(salicylidenaminato)] has been synthesized and its crystal structure has been determined by single-crystal X-ray diffraction method. The compound has a 1D hydrogen-bonded extended structure. Both the FT-IR spectrum and the electrospray ionization mass spectrum (ESI-MS) of the title compound have been recorded. The thermogravimetric analysis has also been carried out. Magnetic calculations showed the presence of antiferromagnetic exchange interactions between the manganese(III) ions through hydrogen bonds with J = -4.0 cm-1.
KW - ID extended structure
KW - Magnetic properties
KW - Manganese(III) complex
KW - Schiff base complex
KW - Synthesis
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U2 - 10.1016/S0022-2860(01)00474-4
DO - 10.1016/S0022-2860(01)00474-4
M3 - Article
AN - SCOPUS:0035424928
SN - 0022-2860
VL - 570
SP - 137
EP - 143
JO - Journal of Molecular Structure
JF - Journal of Molecular Structure
IS - 1-3
ER -