Synthesis, crystal and molecular structure and magnetic properties of [Mn(saloph)(N3)(Ch3OH)]

Kou Lin Zhang; Yan Xu; You Song; Yong Zhang; Zheng Wang; Xiao Zeng You

doi:10.1016/S0022-2860(01)00474-4

Synthesis, crystal and molecular structure and magnetic properties of [Mn(saloph)(N₃)(Ch₃OH)]

Kou Lin Zhang
, Yan Xu
, You Song
, Yong Zhang
, Zheng Wang
, Xiao Zeng You

Department of Chemistry and Chemical Biology

Nanjing University

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The mononuclear manganese(III) complex of formula [Mn(saloph)(N₃)(CH₃OH)] [saloph = N,N'-o-phenylenebis(salicylidenaminato)] has been synthesized and its crystal structure has been determined by single-crystal X-ray diffraction method. The compound has a 1D hydrogen-bonded extended structure. Both the FT-IR spectrum and the electrospray ionization mass spectrum (ESI-MS) of the title compound have been recorded. The thermogravimetric analysis has also been carried out. Magnetic calculations showed the presence of antiferromagnetic exchange interactions between the manganese(III) ions through hydrogen bonds with J = -4.0 cm^-1.

Original language	English
Pages (from-to)	137-143
Number of pages	7
Journal	Journal of Molecular Structure
Volume	570
Issue number	1-3
DOIs	https://doi.org/10.1016/S0022-2860(01)00474-4
State	Published - 1 Aug 2001

Keywords

ID extended structure
Magnetic properties
Manganese(III) complex
Schiff base complex
Synthesis

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10.1016/S0022-2860(01)00474-4

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title = "Synthesis, crystal and molecular structure and magnetic properties of [Mn(saloph)(N3)(Ch3OH)]",

abstract = "The mononuclear manganese(III) complex of formula [Mn(saloph)(N3)(CH3OH)] [saloph = N,N'-o-phenylenebis(salicylidenaminato)] has been synthesized and its crystal structure has been determined by single-crystal X-ray diffraction method. The compound has a 1D hydrogen-bonded extended structure. Both the FT-IR spectrum and the electrospray ionization mass spectrum (ESI-MS) of the title compound have been recorded. The thermogravimetric analysis has also been carried out. Magnetic calculations showed the presence of antiferromagnetic exchange interactions between the manganese(III) ions through hydrogen bonds with J = -4.0 cm-1.",

keywords = "ID extended structure, Magnetic properties, Manganese(III) complex, Schiff base complex, Synthesis",

author = "Zhang, \{Kou Lin\} and Yan Xu and You Song and Yong Zhang and Zheng Wang and You, \{Xiao Zeng\}",

year = "2001",

month = aug,

day = "1",

doi = "10.1016/S0022-2860(01)00474-4",

language = "English",

volume = "570",

pages = "137--143",

number = "1-3",

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TY - JOUR

T1 - Synthesis, crystal and molecular structure and magnetic properties of [Mn(saloph)(N3)(Ch3OH)]

AU - Zhang, Kou Lin

AU - Xu, Yan

AU - Song, You

AU - Zhang, Yong

AU - Wang, Zheng

AU - You, Xiao Zeng

PY - 2001/8/1

Y1 - 2001/8/1

N2 - The mononuclear manganese(III) complex of formula [Mn(saloph)(N3)(CH3OH)] [saloph = N,N'-o-phenylenebis(salicylidenaminato)] has been synthesized and its crystal structure has been determined by single-crystal X-ray diffraction method. The compound has a 1D hydrogen-bonded extended structure. Both the FT-IR spectrum and the electrospray ionization mass spectrum (ESI-MS) of the title compound have been recorded. The thermogravimetric analysis has also been carried out. Magnetic calculations showed the presence of antiferromagnetic exchange interactions between the manganese(III) ions through hydrogen bonds with J = -4.0 cm-1.

AB - The mononuclear manganese(III) complex of formula [Mn(saloph)(N3)(CH3OH)] [saloph = N,N'-o-phenylenebis(salicylidenaminato)] has been synthesized and its crystal structure has been determined by single-crystal X-ray diffraction method. The compound has a 1D hydrogen-bonded extended structure. Both the FT-IR spectrum and the electrospray ionization mass spectrum (ESI-MS) of the title compound have been recorded. The thermogravimetric analysis has also been carried out. Magnetic calculations showed the presence of antiferromagnetic exchange interactions between the manganese(III) ions through hydrogen bonds with J = -4.0 cm-1.

KW - ID extended structure

KW - Magnetic properties

KW - Manganese(III) complex

KW - Schiff base complex

KW - Synthesis

UR - https://www.scopus.com/pages/publications/0035424928

UR - https://www.scopus.com/pages/publications/0035424928#tab=citedBy

U2 - 10.1016/S0022-2860(01)00474-4

DO - 10.1016/S0022-2860(01)00474-4

M3 - Article

AN - SCOPUS:0035424928

SN - 0022-2860

VL - 570

SP - 137

EP - 143

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

Synthesis, crystal and molecular structure and magnetic properties of [Mn(saloph)(N₃)(Ch₃OH)]

Abstract

Keywords

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