TY - JOUR
T1 - Synthesis of [2,3,4,5,6-2H5]phenyl glucosinolate
AU - Bialecki, Jason B.
AU - Ruzicka, Josef
AU - Attygalle, Athula B.
PY - 2007/7
Y1 - 2007/7
N2 - Starting from commercially available [2,3,4,5,6-2H 5]benzoic acid, [2,3,4,5,6-2H5]phenyl glucosinolate was synthesized. Under negative-ion electrospray-ionization mass spectrometric conditions, this compound affords a peak at m/z 399. Since this m/z value is not known from the ions derived from natural glucosinolates, the [2,3,4,5,6-2H5]phenyl glucosinolate reported here is useful as an internal standard for the quantification of glucosinolates by negative-ion mass spectrometry (MS) and liquid chromatography (LC)/MS techniques.
AB - Starting from commercially available [2,3,4,5,6-2H 5]benzoic acid, [2,3,4,5,6-2H5]phenyl glucosinolate was synthesized. Under negative-ion electrospray-ionization mass spectrometric conditions, this compound affords a peak at m/z 399. Since this m/z value is not known from the ions derived from natural glucosinolates, the [2,3,4,5,6-2H5]phenyl glucosinolate reported here is useful as an internal standard for the quantification of glucosinolates by negative-ion mass spectrometry (MS) and liquid chromatography (LC)/MS techniques.
KW - Collision-induced dissociation (CID)
KW - Electrospray-ionization mass spectrometry
KW - Glucosinolates
KW - Internal standard
KW - Phenyl glucosinolate
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U2 - 10.1002/jlcr.1407
DO - 10.1002/jlcr.1407
M3 - Article
AN - SCOPUS:34548825727
SN - 0362-4803
VL - 50
SP - 711
EP - 715
JO - Journal of Labelled Compounds and Radiopharmaceuticals
JF - Journal of Labelled Compounds and Radiopharmaceuticals
IS - 8
ER -