The preparation, crystal structure and properties of a mixed-ligand copper(I) complex [CuI(PPh3)(DPPZ)]·DMF

Yu Jun Shi; Shu Jian Chen; Bin Huang; Xue Tai Chen; Yong Zhang; Xiao Zeng You

doi:10.1016/S0022-2860(02)00565-3

The preparation, crystal structure and properties of a mixed-ligand copper(I) complex [CuI(PPh₃)(DPPZ)]·DMF

Yu Jun Shi
, Shu Jian Chen
, Bin Huang
, Xue Tai Chen
, Yong Zhang
, Xiao Zeng You

Department of Chemistry and Chemical Biology

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

The mixed ligand mononuclear copper(I) complex of formula [CuI(PPh₃)(DPPZ)]·DMF (DPPZ = dipyrido[3,2,-a:2′,3′-c]phenazine) has been synthesized and has been characterized by single-crystal X-ray diffraction method, FT-IR spectrum, the electrospray ionization mass spectrum and the thermogravimetric analysis. The pairwise π-π stacking between DPPZ ligands exists through the crystal lattice.

Original language	English
Pages (from-to)	27-32
Number of pages	6
Journal	Journal of Molecular Structure
Volume	650
Issue number	1-3
DOIs	https://doi.org/10.1016/S0022-2860(02)00565-3
State	Published - 13 May 2003

Keywords

Copper(I) complex
Crystal structure
DPPZ
Electrospray ionization mass spectrum

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10.1016/S0022-2860(02)00565-3

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title = "The preparation, crystal structure and properties of a mixed-ligand copper(I) complex [CuI(PPh3)(DPPZ)]·DMF",

abstract = "The mixed ligand mononuclear copper(I) complex of formula [CuI(PPh3)(DPPZ)]·DMF (DPPZ = dipyrido[3,2,-a:2′,3′-c]phenazine) has been synthesized and has been characterized by single-crystal X-ray diffraction method, FT-IR spectrum, the electrospray ionization mass spectrum and the thermogravimetric analysis. The pairwise π-π stacking between DPPZ ligands exists through the crystal lattice.",

keywords = "Copper(I) complex, Crystal structure, DPPZ, Electrospray ionization mass spectrum",

author = "Shi, \{Yu Jun\} and Chen, \{Shu Jian\} and Bin Huang and Chen, \{Xue Tai\} and Yong Zhang and You, \{Xiao Zeng\}",

year = "2003",

month = may,

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doi = "10.1016/S0022-2860(02)00565-3",

language = "English",

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T1 - The preparation, crystal structure and properties of a mixed-ligand copper(I) complex [CuI(PPh3)(DPPZ)]·DMF

AU - Shi, Yu Jun

AU - Chen, Shu Jian

AU - Huang, Bin

AU - Chen, Xue Tai

AU - Zhang, Yong

AU - You, Xiao Zeng

PY - 2003/5/13

Y1 - 2003/5/13

N2 - The mixed ligand mononuclear copper(I) complex of formula [CuI(PPh3)(DPPZ)]·DMF (DPPZ = dipyrido[3,2,-a:2′,3′-c]phenazine) has been synthesized and has been characterized by single-crystal X-ray diffraction method, FT-IR spectrum, the electrospray ionization mass spectrum and the thermogravimetric analysis. The pairwise π-π stacking between DPPZ ligands exists through the crystal lattice.

AB - The mixed ligand mononuclear copper(I) complex of formula [CuI(PPh3)(DPPZ)]·DMF (DPPZ = dipyrido[3,2,-a:2′,3′-c]phenazine) has been synthesized and has been characterized by single-crystal X-ray diffraction method, FT-IR spectrum, the electrospray ionization mass spectrum and the thermogravimetric analysis. The pairwise π-π stacking between DPPZ ligands exists through the crystal lattice.

KW - Copper(I) complex

KW - Crystal structure

KW - DPPZ

KW - Electrospray ionization mass spectrum

UR - https://www.scopus.com/pages/publications/0037651265

UR - https://www.scopus.com/pages/publications/0037651265#tab=citedBy

U2 - 10.1016/S0022-2860(02)00565-3

DO - 10.1016/S0022-2860(02)00565-3

M3 - Article

AN - SCOPUS:0037651265

SN - 0022-2860

VL - 650

SP - 27

EP - 32

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

The preparation, crystal structure and properties of a mixed-ligand copper(I) complex [CuI(PPh₃)(DPPZ)]·DMF

Abstract

Keywords

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