TY - GEN
T1 - Tich nanofibers based dye-sensitized solar cells
AU - Li, Jinwei
AU - Xu, Shiyou
AU - Shi, Yong
PY - 2010
Y1 - 2010
N2 - Dye sensitized solar cells (DSSCs) are promising photovoltaic devices as they offer advantages such as low cost and easy for fabrication et al. The key part of the original DSSC is a sintered film of nanoparticles which has a large surface area for the absorption of dyes. It has been reported that boundaries of nanoparticles diminish the efficiency of charge transport in the nanoparticle network, and lead to charge-carrier recombination. The one dimensional morphology of the nanofiber is believed to improve electron transport efficiency without sacrificing the high specific surface area for the adsorption of dyes. In this paper, TiO2 nanofibers are used to replace TiO2 nanoparticles in the DSSC. The film of nanofibers was synthesized by electrospinning process and collected on the transparent conductive glass substrate. The precursor used for the electrospinning of the nanofiber consists of titanium (IV) isopropoxide, acetate acid, ethanol and polyvinylpyrrolidone(PVP). After the electrospinning process, nanofibers were pretreated at 120°C for 2 hours and annealed at 500°C in atmosphere for another 2 hours. Then DSSC with the film of TiO2 nanofibers were assembled and characterized through electrical measurements. Open circuit voltage of 0.7V and short circuit current densities of 0.45mA /cm2 were achieved.
AB - Dye sensitized solar cells (DSSCs) are promising photovoltaic devices as they offer advantages such as low cost and easy for fabrication et al. The key part of the original DSSC is a sintered film of nanoparticles which has a large surface area for the absorption of dyes. It has been reported that boundaries of nanoparticles diminish the efficiency of charge transport in the nanoparticle network, and lead to charge-carrier recombination. The one dimensional morphology of the nanofiber is believed to improve electron transport efficiency without sacrificing the high specific surface area for the adsorption of dyes. In this paper, TiO2 nanofibers are used to replace TiO2 nanoparticles in the DSSC. The film of nanofibers was synthesized by electrospinning process and collected on the transparent conductive glass substrate. The precursor used for the electrospinning of the nanofiber consists of titanium (IV) isopropoxide, acetate acid, ethanol and polyvinylpyrrolidone(PVP). After the electrospinning process, nanofibers were pretreated at 120°C for 2 hours and annealed at 500°C in atmosphere for another 2 hours. Then DSSC with the film of TiO2 nanofibers were assembled and characterized through electrical measurements. Open circuit voltage of 0.7V and short circuit current densities of 0.45mA /cm2 were achieved.
UR - http://www.scopus.com/inward/record.url?scp=77954294206&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=77954294206&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:77954294206
SN - 9780791843857
T3 - ASME International Mechanical Engineering Congress and Exposition, Proceedings
SP - 387
EP - 390
BT - Proceedings of the ASME International Mechanical Engineering Congress and Exposition 2009, IMECE 2009
T2 - ASME 2009 International Mechanical Engineering Congress and Exposition, IMECE2009
Y2 - 13 November 2009 through 19 November 2009
ER -