Water-promoted cascade synthesis of α-arylaldehydes from arylalkenes using N-halosuccinimides: An avenue for asymmetric oxidation using Cinchona organocatalysis

Abhishek Sharma; Naina Sharma; Rakesh Kumar; Upendra K. Sharma; Arun K. Sinha

doi:10.1039/b908717f

Water-promoted cascade synthesis of α-arylaldehydes from arylalkenes using N-halosuccinimides: An avenue for asymmetric oxidation using Cinchona organocatalysis

Abhishek Sharma
, Naina Sharma
, Rakesh Kumar
, Upendra K. Sharma
, Arun K. Sinha

Department of Chemistry and Chemical Biology

CSIR - Institute of Himalayan Bioresource Technology

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

The direct oxidation of arylalkenes into α-arylaldehydes is achieved for the first time in water without relying on transition metal catalysts, and a novel organocatalytic enantioselective approach is also explored to provide up to 30% ee in initial investigations.

Original language	English
Pages (from-to)	5299-5301
Number of pages	3
Journal	Chemical Communications
Issue number	35
DOIs	https://doi.org/10.1039/b908717f
State	Published - 2009

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title = "Water-promoted cascade synthesis of α-arylaldehydes from arylalkenes using N-halosuccinimides: An avenue for asymmetric oxidation using Cinchona organocatalysis",

abstract = "The direct oxidation of arylalkenes into α-arylaldehydes is achieved for the first time in water without relying on transition metal catalysts, and a novel organocatalytic enantioselective approach is also explored to provide up to 30\% ee in initial investigations.",

author = "Abhishek Sharma and Naina Sharma and Rakesh Kumar and Sharma, \{Upendra K.\} and Sinha, \{Arun K.\}",

year = "2009",

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T1 - Water-promoted cascade synthesis of α-arylaldehydes from arylalkenes using N-halosuccinimides

T2 - An avenue for asymmetric oxidation using Cinchona organocatalysis

AU - Sharma, Abhishek

AU - Sharma, Naina

AU - Kumar, Rakesh

AU - Sharma, Upendra K.

AU - Sinha, Arun K.

PY - 2009

Y1 - 2009

N2 - The direct oxidation of arylalkenes into α-arylaldehydes is achieved for the first time in water without relying on transition metal catalysts, and a novel organocatalytic enantioselective approach is also explored to provide up to 30% ee in initial investigations.

AB - The direct oxidation of arylalkenes into α-arylaldehydes is achieved for the first time in water without relying on transition metal catalysts, and a novel organocatalytic enantioselective approach is also explored to provide up to 30% ee in initial investigations.

UR - https://www.scopus.com/pages/publications/69549126330

UR - https://www.scopus.com/pages/publications/69549126330#tab=citedBy

U2 - 10.1039/b908717f

DO - 10.1039/b908717f

M3 - Article

C2 - 19707652

AN - SCOPUS:69549126330

SN - 1359-7345

SP - 5299

EP - 5301

JO - Chemical Communications

JF - Chemical Communications

IS - 35

ER -

Water-promoted cascade synthesis of α-arylaldehydes from arylalkenes using N-halosuccinimides: An avenue for asymmetric oxidation using Cinchona organocatalysis

Abstract

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